Kerberos authentication is a ticketing system giving users various permissions to access various systems.
Kerberos uses Service Principal Names (SPNs) as account identifiers.
If you can authenticate to Active Directory, you can request a ticket for a given SPN.
Retrieve SPNs with impacket-GetUserSPNs.
Obtaining this ticket, you can then try to crack it using hashcat -m 13100.
Once cracked, go to town, login. Do the things.